Avios offer a wide range of partners where you can collect and spend your Avios points.
So that you can start collecting points every time you use your Monese card in participating places, you’ll need to link your Avios account with your Monese account.
To do this, follow these steps here.
You can read more about it on the Avios official website at https://www.avios.com/eu/en/faqs