For security reasons all online payments are blocked if the wrong card verification code (CVC) is entered 3 times. This is to safeguard your funds in case someone tries to use your card without your authorisation.
Your card becomes usable again automatically after 00:00 midnight (UK time). You can always check your card CVC on the back of your card.
Monese support can not lift this type of block remotely, you will have to wait until midnight for the card to become usable again automatically.